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Abstract Microstructure observations in the Pacific cold tongue reveal that turbulence often penetrates into the thermocline, producing hundreds of watts per square meter of downward heat transport during nighttime and early morning. However, virtually all observations of this deep-cycle turbulence (DCT) are from 0°, 140°W. Here, a hierarchy of ocean process simulations, including submesoscale-permitting regional models and turbulence-permitting large-eddy simulations (LES) embedded in a regional model, provide insight into mixing and DCT at and beyond 0°, 140°W. A regional hindcast quantifies the spatiotemporal variability of subsurface turbulent heat fluxes throughout the cold tongue from 1999 to 2016. Mean subsurface turbulent fluxes are strongest (∼100 W m −2 ) within 2° of the equator, slightly (∼10 W m −2 ) stronger in the northern than Southern Hemisphere throughout the cold tongue, and correlated with surface heat fluxes ( r 2 = 0.7). The seasonal cycle of the subsurface heat flux, which does not covary with the surface heat flux, ranges from 150 W m −2 near the equator to 30 and 10 W m −2 at 4°N and 4°S, respectively. Aseasonal variability of the subsurface heat flux is logarithmically distributed, covaries spatially with the time-mean flux, and is highlighted in 34-day LES of boreal autumn at 0° and 3°N, 140°W. Intense DCT occurs frequently above the undercurrent at 0° and intermittently at 3°N. Daily mean heat fluxes scale with the bulk vertical shear and the wind stress, which together explain ∼90% of the daily variance across both LES. Observational validation of the scaling at 0°, 140°W is encouraging, but observations beyond 0°, 140°W are needed to facilitate refinement of mixing parameterization in ocean models. Significance Statement This work is a fundamental contribution to a broad community effort to improve global long-range weather and climate forecast models used for seasonal to longer-term prediction. Much of the predictability on seasonal time scales is derived from the slow evolution of the upper eastern equatorial Pacific Ocean as it varies between El Niño and La Niña conditions. This study presents state-of-the-art high-resolution regional numerical simulations of ocean turbulence and mixing in the eastern equatorial Pacific. The results inform future planning for field work as well as future efforts to refine the representation of ocean mixing in global forecast models. 

As climate‐driven El Niño Southern Oscillation (ENSO) events are projected to increase in frequency and severity, much attention has focused on impacts regarding ecosystem productivity and carbon balance in Amazonian rainforests, with comparatively little attention given to carbon dynamics in fluvial ecosystems. In this study, we compared the wet 2012 La Niña period to the following normal hydrologic period in the Amazon River. Elevated water flux during the La Niña period was accompanied by dilution of inorganic ion concentrations. Furthermore, the La Niña period exported 2.77 Tg C yr⁻¹more dissolved organic carbon (DOC) than the normal period, an increase greater than the annual amount of DOC exported by the Mississippi River. Using ultra‐high‐resolution mass spectrometry, we detected both intra‐ and interannual differences in dissolved organic matter (DOM) composition, revealing that DOM exported during the dry season and the normal period was more aliphatic, whereas compounds in the wet season and following the La Niña event were more aromatic, with ramifications for its environmental role. Furthermore, as this study has the highest temporal resolution DOM compositional data for the Amazon River to‐date we showed that compounds were highly correlated to a 6‐month lag in Pacific temperature and pressure anomalies, suggesting that ENSO events could impact DOM composition exported to the Atlantic Ocean. Therefore, as ENSO events increase in frequency and severity into the future it seems likely that there will be downstream consequences for the fate of Amazon Basin‐derived DOM concurrent with lag periods as described here.

 

Climate change is dramatically altering Arctic ecosystems, leading to shifts in the sources, composition, and eventual fate of riverine dissolved organic matter (DOM) in the Arctic Ocean. Here we examine a 6‐year DOM compositional record from the six major Arctic rivers using Fourier‐transform ion cyclotron resonance mass spectrometry paired with dissolved organic carbon isotope data (Δ¹⁴C, δ¹³C) to investigate how seasonality and permafrost influence DOM, and how DOM export may change with warming. Across the pan‐Arctic, DOM molecular composition demonstrates synchrony and stability. Spring freshet brings recently leached terrestrial DOM with a latent high‐energy and potentially bioavailable subsidy, reconciling the historical paradox between freshet DOM's terrestrial bulk signatures and high biolability. Winter features undiluted baseflow DOM sourced from old, microbially degraded groundwater DOM. A stable core Arctic riverine fingerprint (CARF) is present in all samples and may contribute to the potential carbon sink of persistent, aged DOM in the global ocean. Future warming may lead to shifting sources of DOM and export through: (1) flattening Arctic hydrographs and earlier melt modifying the timing and role of the spring high‐energy subsidy; (2) increasing groundwater discharge resulting in a greater fraction of DOM export to the ocean occurring as stable and aged molecules; and (3) increasing contribution of nitrogen/sulfur‐containing DOM from microbial degradation caused by increased connectivity between groundwater and surface waters due to permafrost thaw. Our findings suggest the ubiquitous CARF (which may contribute to oceanic carbon sequestration) underlies predictable variations in riverine DOM composition caused by seasonality and permafrost extent.